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The systemic inflammatory response generated by the production of cytokines and chemokines during intestinal I/R injury might profoundly disrupt the bloodbrain barrier (BBB) (Guo et al., 2025)

Subsequently, we found that the thiol and amine can be added simultaneously to the BDA intermediate to still generate the same 3-thio N -pyrrole heterocycle 2a because of the high nucleophilicity of thiols as compared to amines (entry 3, Fig